Food and Chemical Safety

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Chemical warfare agents

Fact Sheet 1: Overview of Chemicals Defined as Chemical Weapons

What are chemical weapons?

The Chemical Weapons Convention considers chemical weapons to include both the toxic chemicals that are used in warfare, and the munitions and equipment used to disperse them. Toxic chemicals are defined as "any chemical which through its chemical action on life processes can cause death, temporary incapacitation or permanent harm to humans or animals. This includes all such chemicals, regardless of their origin or of their method of production and regardless of whether they are produced in facilities, in munitions or elsewhere."

Today, thousands of poisonous substances are known but only a few are considered suitable for chemical warfare. About 70 different chemicals have been used or stockpiled as CW agents during the 20th century. Today, only a few of these are considered of interest because:

*     A presumptive agent must not only be highly toxic but also "suitably highly toxic" so that it is not too difficult to handle. 

*     The substance must be capable of being stored for long periods without degradation and without corroding the packaging material. 

*     It must be relatively resistant to atmospheric water and oxygen so that it does not lose effect when dispersed. 

*     It must also withstand the heat developed when dispersed by explosion. 

 

The World Health Organization has listed 17 chemical weapons which are grouped as:

*     NERVE AGENTS, for example tabun, sarin and soman. 

*     VESICANTS (blister gases), for example "mustard gas" and other.

*     CHOKING AGENTS (lung irritants), for example phosgene and chloropicrin

*     BLOOD GASES, for example hydrogen

*     TEAR GASES and other disabling chemicals cyanide

War gases" are seldom gases

The CW agents used today are only exceptionally gases. Normally they are liquids or solids, often dispersed in the air in so-called aerosols. An aerosol can penetrate the body through the respiratory organs in the same way as a gas. In order to achieve good ground coverage when dispersed from a high altitude with persistent CW agents the dispersed droplets must be sufficiently large to ensure that they fall within the target area. This can be achieved by dissolving polymers (e.g., polystyrene or rubber products) in the CW agent to make the product highly-viscous or thickened. The result will be that the persistence time and adhesive ability increase which thus complicates decontamination.

ROUTES OF EXPOSURE

SKIN: Systemic poisoning may result from inhalation, dermal exposure and ingestion. Some CW agents can penetrate the skin. This mainly concerns liquids but in some cases also gases and aerosols. Solid substances penetrate the skin slowly unless they happen to be mixed with a suitable solvent. Local damage to the skin may promote absorption.

INHALATION: Chemical agents may be inhaled, or ingested (e.g. through contaminated food or water). The respiratory system is affected by inhalation.

EYES: The eyes are particularly sensitive to chemical agents and may cause the development of symptoms very quickly.

Psychological stress may itself mimic some of the effects of chemical weapons.

Fact Sheets on Chemical Warfare Agents, SDE/SEARO, World Health Organization, New Delhi, India`

 

 

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